This is the tier list for Arknights global, which was released Jan 16th 2020.
Special thanks to Kyo for compiling the info:
Please visit his awesome channel for more Arknights info.
Here is the legend for the tier list:
- S - Top Operators
 - A - Strong Operators
 - B - Good Operators
 - C - Decent Operators
 - D - Normal Operators
 - Specialist - Useful in certain situations
 
The tier list also takes into consideration the max level of the operator alongside their skills they provide. We have grouped the units based on their class below for the summary.
Snipers (Single Target)
Exusiai (6★, S)

- Strong Burst Damage
 - Increase attack damage and max life of herself and random ally
 
Blue Poison (5★, A)

- Magic Damage
 - Multiple target skill
 
Platinum (5★, A)

- Long attack range
 - Slower, powerful shots
 
Meteor (4★, B)

- Reduce enemy's armor
 - Strong damage against air units
 
Kroos (4★, C)

Jessica (4★, C)

- Good defense
 
Adnachiel (3★, D)

Rangers (2★, D)

Firewatch (5★, Specialist)

- Good burst damage
 - High attack and long range
 - Hidden effect
 
Provence (5★, Specialist)

- Small attack range
 - Higher damage when close range
 
Sniper AoE
Meteorite (5★, A)

- Strong burst damage
 - Reduce enemy's armor with S2
 
Shirayuki (4★, A)

- Magic damage
 - Slow enemy with S2
 - Long attack range
 
Caster Single Target
Eyjafjalla (6★, S)

- Good damage
 - Buff all caster
 - Weaken enemy magic resist
 - S3 multi target
 
Amiya (5★, A)

- Burst damage
 - True damage on S3
 - Fast charge skill after E2
 
Haze (4★, C)

- Weaken enemy magic resist
 
Steward (3★, C)

- Attacks enemy with the highest armor
 
Durin (2★, D)

Caster AoE
Ifrit (6★, S)

- 5 tiles straight line attack
 - Explosive damage
 - Reduce enemy magic resist
 
Skyfire (5★, A)

- All blocked enemies receive more magic damage
 - Stun on S2
 
Gitano (4★, B)

- Random permanent bonus at depolyment
 - S2 has longer attack range
 
Lava (3★, C)

12F (2★, D)

Guard Single Target
SilverAsh (6★, S)

- Good damage
 - Large attack range
 - Cancel enemy's hidden effect
 - S3 multi target
 
Lappland (5★, A)

- Large attack range
 - Magic damage
 - Cancel enemy's special ability
 
Franka (5★, B)

- Burst damage
 - True damage
 - Highest attack
 
Matoimaru (4★, B)

- Burst damage
 - Heal herself
 
Melantha (3★, B)

- Easy to level
 - High attack
 
Indra (5★, B)

- Dodge physical damage
 - Ignore armor
 - Magic damage
 - Recruit exclusive
 
Frostleaf (4★, B)

- Large attack range
 - Slow enemies
 - Can freeze enemies
 
Mousse (4★, B)

- % to combo
 - Enemy attack debuff
 - Normal attack is magic damage
 
Dobermann (4★, C)

- Good damage
 - Buff to 3 star operators
 
Guard AoE
Specter (5★, A)

- Self heal
 - Immortaity
 - High survivability
 
Savage (5★, B)

- Strong burst damage
 - Exclusive reward from pre-registration
 
Estelle (4★, B)

- Self heal
 - Recruit exclusive
 
Castle-3 (1★, Specialist)

- Attack and armor buff to all allies for 10 seconds after deployment
 
Tank (Defender)
Hoshiguma (6★, S)

- S3 AoE burst damage
 - S2 rebound damage
 - Buff to all defenders
 
Liskarm (5★, A)

- Can stun enemies
 - Magic damage
 - Charge ally's skill points when get hit
 
Croissant (5★, A)

- Can stun and knock enemies
 - % immune to attacks
 
Cuora (4★, A)

- S2 can block 4
 - Self heal
 - High armor
 
Matterhorn (4★, B)

- High magic resist
 
Beagle (3★, C)

- Barrier
 
Noir Corne (2★, D)

Medic Tank
Saria (6★, S)

- AoE heal with S2
 - Give 1 skill point to healed ally
 
Nearl (5★, A)

- Healer
 - Buff to heal effect
 
Gummy (4★, B)

- Healer
 - % stun to enemies
 
Cardigan (3★, D)

- Self heal
 
Vulcan (5★, Specialist)

- S1 become tank and can block 4
 - S2 become fighter with AoE damage
 - Can't be healed
 - Self heal
 - Recruit exclusive
 
Vanguard (Skill CP)
Siege (6★, S)

- AoE damage with S2
 - Buff to all vanguard
 - Charge skill points when enemy die nearby
 
Texas (5★, A)

- AoE stun
 - If in team, you will start the game with 1/2 extra cost
 
Zima (5★, A)

- Herself cost-1
 - At E2, all vanguard's cost-1
 - S2 give buff to all vanguards
 
Scavenger (4★, B)

- Buff if there are no allies nearby
 
Courier (4★, B)

Vanilla (3★, C)

Fang (3★, C)

- DP recovery
 
Yato (2★, D)

Vanguard (Kill CP)
Vigna (4★, B)

Plume (3★, C)

Medic Single Target
Shining (6★, A)

- Physical damage shield
 - Increase nearby ally armor
 
Silence (5★, A)

- Increases medic's attack speed
 - Summon heal drone
 
Warfarin (5★, A)

- Gain skill points if enemy dies in her attack range
 - Attack buff with S2
 - Emergency heal
 
Myrrh (4★, B)

- Insta heal on deployment
 - Skills allow her to heal an extra ally
 
Gavial (4★, B)

- Buff on deployment
 - Sustained heal with skills
 
Hibiscus (3★, C)

Ansel (3★, C)

Medic Multi Target
Nightingale (6★, S)

- Magic damage shield
 - Summon Phantom
 - Increase nearby ally's magic resist
 
Ptilopsis (6★, S)

- Increase all ally's skill points charge speed
 - Burst heal with S2
 
Perfumer (4★, B)

- Global heal per second
 
Lancet-2 (1★, Specialist)

Supporter Crowd Control
Angelina (6★, A)

- Attack speed buff to all ally
 - Global heal per second
 
Istina (5★, B)

- Good single target slow down
 
Earthspirit (4★, C)

Orchid (3★, D)

Supporter Buff/Debuff
Pramanix (5★, A)

- Reduce enemy attack speed, armor and magic resist
 - Attack enemy in her attack range will receive extra damage if under 40% hp
 
Sora (5★, A)

- Big attack buff to all ally in her attack range
 - Enemy sleep cc (stun but invincible)
 
Supporter Summon
Mayer (5★, A)

- Summon mecha otter
 - Burst damage
 - stun
 
Deepcolor (4★, C)

- Summon tentacles
 
Specialist Utility
Red (5★)

- Fast revive
 - Stun
 
Gravel 4★

- Fast revive
 
Specialist CC
Manticore 5★

- Hidden effect
 - Slow down
 - Stun
 
Specialist Push Pull
Feater 5★

- Push enemies
 - Slow down
 
Shaw 4★

- Push enemies
 
Cliffheart 5★

- Pull enemies
 - Stun
 
Rope 4★

- Pull enemies
 
